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Donating baby clothes
I did a similar sort of thing recently by donating to a women's refuge.
It was organised via a social worker at the local office of my mutuelle - they even collected the stuff from my place.
There is an organisation called Alternatives which helps pregnant women and mothers of young babies who are always appealing for this kind of thing. They are based near Merode and this is their website: http://www.alternativesbruxelles.be/
If you make an order with cirkle.be (a grocery home delivery service) they will collect your baby stuff for free and pass on to NASCI - a charity in brussels to help mothers